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Electrophile |
Product (% Yield) |
Electrophile |
Product (% Yield) |
---|---|---|---|
EtCHO |
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Me3SiCI |
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PhCHO |
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(MeO)2SO2 |
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PhCOMe |
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H2O |
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CF3CHO |
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PhCH2OH |
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(C2F5)2CO |
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PhCONH2 |
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PhCOCI |
![]() |
CHF(CO2Et)2 |
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Nucleophile |
Producta |
Yield (%) |
---|---|---|
BuLi |
71 |
|
PhLi |
64 |
|
PhMgBr |
48 |
|
Red-AI |
55 |
|
aMetal enolates 5 thus formed were isolated after acylation with an acyl chloride. |
Appendix
Chemical Abstracts Nomenclature (Collective Index Number);
(Registry Number)
Lithium pentafluoropropen-2-olate: 1-Propen-2-ol, 1,1,3,3,3-pentafluoro-, lithium salt (12); (116019-90-0)
4-Hydroxy-1,1,1,3,3-pentafluoro-2-hexanone hydrate: 2,2,4-Hexanetriol, 1,1,1,3,3-pentafluoro- (12); (119333-90-3)
Hexafluoroisopropanol alcohol: 2-Propanol, 1,1,1,3,3,3-hexafluoro- (8,9); (920-66-1) Butyllithium: Lithium, butyl- (8,9); (109-72-8)
Propionaldehyde (8); Propanal (9); (123-38-6)