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Properties of substance:
methanesulfonic acid
Group of substances:
organic
Empirical formula (Hill's system for organic substances):
CH
4
O
3
S
Structural formula as text:
CH3SO3H
Molar/atomic mass: 96.106
Melting point (°C):
20
CAS №: 75-75-2
Solubility (g/100 g of solvent):
benzene
: 1.5 (27°C) [
Ref.
]
diethyl disulfide
: 0.47 (27°C) [
Ref.
]
ethanol
: soluble [
Ref.
]
hexane
: insoluble [
Ref.
]
methylcyclopentane: insoluble [
Ref.
]
o-chlorotoluene: 0.23 (27°C) [
Ref.
]
toluene
: 0.38 (27°C) [
Ref.
]
water
: miscible [
Ref.
]
Density:
1.4844 (20°C, g/cm
3
)
Vapour pressure (Torr):
1 (122°C)
10 (167°C)
Dissociation:
H
0
(1) = -7.86 (25°C)
H
0
(1) = -3.75 (25°C, water)
pK
a
(1) = 0 (25°C, water)
Intrinsic gas-phase acidities ΔG
acid
(kJ/mol)
1318 (g) [
Ref.
]
LD
50
(mg/kg):
708 (rats, oral)
2400 (mice, oral)
References:
Dictionary of organic compounds. - Vol. 2, Eccaine - Myrtillin chloride. - London, 1946. - pp. 596
Seidell A. Solubilities of organic compounds. - 3ed., vol.2. - New York: D. Van Nostrand Company, 1941. - pp. 64
Stahl P.H., Wermuth C.G. Handbook of Pharmaceutical Salts: Properties, Selection, and Use. - Wiley-VCH, 2002. - pp. 294-295
The Merck Index. - 15th ed. - Royal Society of Chemistry, 2013. - pp. 1105
Альберт А., Сержент Е. Константы ионизации кислот и оснований. - М.-Л.: Химия, 1964. - pp. 127 [Russian]
Справочник по растворимости. - Т.1, Кн.1. - М.-Л.: ИАН СССР, 1961. - pp. 374 [Russian]
Сьютер Ч. Химия органических соединений серы. - Ч. 1. - М.: ИИЛ, 1950. - pp. 110, 115 [Russian]
Химическая энциклопедия. - Т. 5. - М.: Советская энциклопедия, 1999. - pp. 216 [Russian]
Химический энциклопедический словарь. - Под ред. Кнунянц И.Л. - М.: Советская энциклопедия, 1983. - pp. 327 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru