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Properties of substance:
aluminum bromide
Synonyms:
aluminium bromide
Group of substances:
inorganic
Physical appearance:
colorless monoclinic crystals
Empirical formula (Hill's system for organic substances):
AlBr
3
Structural formula as text:
AlBr3
Molar/atomic mass: 266.69
Melting point (°C):
97.5
Boiling point (°C):
256.3
CAS №: 7727-15-3
Solubility (g/100 g of solvent):
1,2-dibromoethane
: 72.71 (20°C) [
Ref.
]
acetone
: soluble [
Ref.
]
arsenic tribromide
: very soluble [
Ref.
]
benzene
: 86.92 (20°C) [
Ref.
]
benzonitrile
: 37.87 (25°C) [
Ref.
]
benzophenone
: 44.72 (60°C) [
Ref.
]
benzoyl chloride
: 50.83 (20°C) [
Ref.
]
bromine liquid
: soluble [
Ref.
]
bromoethane
: 72.7 (20°C) [
Ref.
]
carbon disulphide
: 142.72 (20°C) [
Ref.
]
diethyl ether
: soluble [
Ref.
]
ethanol
: soluble [
Ref.
]
hydrogen bromide
: 2.2 (-80°C) [
Ref.
]
iodine monochloride
: soluble [
Ref.
]
nitrobenzene
: 97.63 (30°C) [
Ref.
]
p-xylene
: 55.52 (20°C) [
Ref.
]
phosphorus(V) trichloride oxide
: 15.3 (20°C) [
Ref.
]
pyridine
: 4.01 (20°C) [
Ref.
]
sulfur dioxide
: 0.016 (0°C) [
Ref.
]
thionyl chloride
: soluble [
Ref.
]
toluene
: 73.91 (20°C) [
Ref.
]
water
: soluble [
Ref.
]
Properties of solutions:
10% (wt.), solvent - water
Density (g/cm
3
) = 1.0792 (20°)
22% (wt.), solvent - water
Density (g/cm
3
) = 1.1928 (20°)
26,5% (wt.), solvent - water
Density (g/cm
3
) = 1.2967 (25°)
Hygroscopic:
yes
Density:
3.01 (25°C, g/cm
3
)
2.64 (100°C, g/cm
3
)
Reactions:
Yeild 70%. [
Ref.1
]
BF
3
+ AlBr
3
→ BBr
3
+ AlF
3
Vapour pressure (Torr):
1 (81°C)
10 (118°C)
100 (178°C)
Permittivity (dielectric constant):
3.38 (100°C)
Standard molar enthalpy (heat) of formation Δ
f
H
0
(298.15 K, kJ/mol):
-513.4 (s)
Standard molar Gibbs energy of formation Δ
f
G
0
(298.15 K, kJ/mol):
-490.6 (s)
Standard molar entropy S
0
(298.15 K, J/(mol·K)):
180.2 (s)
Molar heat capacity at constant pressure C
p
(298.15 K, J/(mol·K)):
100.5 (s)
Molar enthalpy (heat) of fusion Δ
fus
H (kJ/mol):
11.25
Enthalpy (heat) of vaporization Δ
vap
H (kJ/mol):
50.2
LD
50
(mg/kg):
1600 (rats, oral)
References:
Comey A. M., Hahn D. A. A dictionary of Chemical Solubilities Inorganic. - 2 ed. - New York, The MacMillan Company, 1921. - pp. 7
Lewis R.J. Sax's Dangerous Properties of Industrial Materials. - 11ed. - Wiley-interscience, 2004. - pp. 131
Patnaik P. Handbook of inorganic chemicals. - McGraw-Hill, 2003. - pp. 4-5
Perry D.L. Handbook of Inorganic Compounds. - 2nd ed. - CRC Press, 2011. - pp. 4
Seidell A. Solubilities of inorganic and metal organic compounds. - 3ed., vol.1. - New York: D. Van Nostrand Company, 1940. - pp. 78-83
Ахадов Я.Ю. Диэлектрические параметры чистых жидкостей. - М.: Издательство МАИ, 1999. - pp. 157 [Russian]
Рабинович В.А., Хавин З.Я. Краткий химический справочник. - Л.: Химия, 1977. - pp. 52 [Russian]
Справочник по растворимости. - Т.1, Кн.1. - М.-Л.: ИАН СССР, 1961. - pp. 857-862 [Russian]
Справочник химика. - Т. 2. - Л.-М.: Химия, 1964. - pp. 18-19 [Russian]
Химический энциклопедический словарь. - Под ред. Кнунянц И.Л. - М.: Советская энциклопедия, 1983. - pp. 28 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru