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Properties of substance:
di-tert-butyl peroxide
Group of substances:
organic
Physical appearance:
colorless liquid
Empirical formula (Hill's system for organic substances):
C
8
H
1
8
O
2
Structural formula as text:
(CH3)3COOC(CH3)3
Molar/atomic mass: 146.227
Melting point (°C):
-20--18
Boiling point (°C):
108
CAS №: 110-05-4
Solubility (g/100 g of solvent):
acetone
: miscible [
Ref.
]
carbon tetrachloride
: soluble [
Ref.
]
ligroin: soluble [
Ref.
]
water
: insoluble [
Ref.
]
Density:
0.704 (20°C, g/cm
3
)
Reactions of synthesis:
[
Ref.1
]
3(CH
3
)
3
COH + 2H
2
O
2
→ (CH
3
)
3
COOC(CH
3
)
3
+ (CH
3
)
3
COOH + 3H
2
O
Reactions:
[
Ref.1
]
(CH
3
)
3
COOC(CH
3
)
3
+ H
2
→ 2(CH
3
)
3
COH
[
Ref.1
]
(CH
3
)
3
COOC(CH
3
)
3
+ H
2
→ 2(CH
3
)
3
COH
[
Ref.1
]
(CH
3
)
3
COOC(CH
3
)
3
+ SO
2
+ Cl
2
→ (CH
3
)
3
COOC(CH
3
)
2
CH
2
SO
2
Cl + HCl
References:
CRC Handbook of Chemistry and Physics. - 95ed. - CRC Press, 2014. - pp. 3-156
Химическая энциклопедия. - Т. 1. - М.: Советская энциклопедия, 1988. - pp. 337-338 [Russian]
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© Collected Ruslan Anatolievich Kiper, burewestnik@mail.ru
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